Si photocathode with Ag-supported dendritic Cu catalyst for CO2 reduction

Si photocathodes integrated with Ag-supported dendritic Cu catalysts are used to perform light-driven reduction of CO2 to C2 and C3 products in aqueous solution. A back illumination geometry with an n-type Si absorber was used to permit the use of absorbing metallic catalysts. Selective carrier collection was accomplished by a p+ implantation on the illumination side and an n+ implantation followed by atomic layer deposition of TiO2 on the electrolyte site. The Ag-supported dendritic Cu CO2 reduction catalyst was formed by evaporation of Ag followed by high-rate electrodeposition of Cu to form a high surface area structure. Under simulated 1 sun illumination in 0.1 M CsHCO3 saturated with CO2, the photovoltage generated by the Si (∼600 mV) enables C2 and C3 products to be produced at -0.4 vs. RHE. Texturing of both sides of the Si increases the light-limited current density, due to reduced reflection on the illumination side, and also deceases the onset potential. Under simulated diurnal illumination conditions photocathodes maintain over 60% faradaic efficiency to hydrocarbon and oxygenate products (mainly ethylene, ethanol, propanol) for several days. After 10 days of testing, contamination from the counter electrode is observed, which causes an increase in hydrogen production. This effect is mitigated by a regeneration procedure which restores the original catalyst selectivity. A tandem, self-powered CO2 reduction device was formed by coupling a Si photocathode with two series-connected semitransparent CH3NH3PbI3 perovskite solar cells, achieving an efficiency for the conversion of sunlight to hydrocarbons and oxygenates of 1.5% (3.5% for all products)

Condensation in microchannels – Surface tension dominated regime

This paper was presented at the 2nd Micro and Nano Flows Conference (MNF2009), which was held at Brunel University, West London, UK. The conference was organised by Brunel University and supported by the Institution of Mechanical Engineers, IPEM, the Italian Union of Thermofluid dynamics, the Process Intensification Network, HEXAG - the Heat Exchange Action Group and the Institute of Mathematics and its Applications.A theoretical model, developed by the authors, for condensation in microchannels takes account of the effects of gravity, streamwise shear stress on the condensate surface as well as the transverse pressure gradient due to surface tension in the presence of change in condensate surface curvature. Numerical results have been generated for various channel shapes, dimensions and inclinations and for various fluids, vapourto-surface temperature differences and vapour mass fluxes. It is found that, over a certain length of channel, the local mean (around the channel perimeter) heat-transfer coefficient is essentially independent of gravity (including inclination of the channel) and surface shear stress and depends only on surface tension. For the surface tension dominated regime an equation for the Nusselt number, as a function of a single dimensionless group analogous to that occurring in the simple Nusselt theory except that the gravity is replaced by surface tension, has been derived both on the basis of dimensional analysis and by approximate theory. The equation represents all of the data satisfactorily

A note on the CLT of the LSS for sample covariance matrix from a spiked population model

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All-optically Control of Light Propagation in Valley-Hall Topological Waveguides of Graphene Metasurfaces

We study the influence of graphene Kerr effect on valley-Hall topological modes of a graphene plasmonic crystal waveguide. Extra air holes are introduced to break the spatial-inversion symmetry of the plasmonic metasurface, which can be performed using e-beam lithography. As a result, a gapless Dirac cone and topologically protected edge modes form inside the nontrivial frequency bandgap. Taking advantage of the fact that graphene is a nonlinear optical material possessing an extremely large Kerr coefficient, we demonstrate that an all-optical switch can be implemented in this topological photonic system by controlling an optical signal propagating in the waveguide via a pump beam injected into the bulk modes of the metasurface. This work may lead to new graphene-based active topological photonic nanodevices

Valley-Hall Topological Transport in Graphene Plasmonic Crystal Waveguides

Due to immunity to disorder and structural imperfections, topologically-protected plasmonic modes have recently attracted increasing attention. Here, we introduce two different mechanisms to construct valley-Hall domain-wall interface waveguides in graphene plasmonic crystal to mimic the quantum valley-Hall effect. In the first case, we break the in-plane spatial inversion symmetry of a single-layer graphene plasmonic crystal waveguide to achieve valley-Hall topological characteristics, whereas in the second case, we break the out-of-plane spatial inversion symmetry of a bi-layer graphene plasmonic crystal waveguide to implement the analog quantum valley-Hall effect. A molecular sensor based on this valley-Hall topological transport phenomenon is also be presented

Evacuation Planning Based on the Contraflow Technique With Consideration of Evacuation Priorities and Traffic Setup Time

Evacuation planning with the contraflow technique is a complex planning problem. The problem is further complicated when more realistic situations such as evacuation priorities and the setup time for the contraflow operation are considered. Such a complex problem has yet to be discussed in the present literature. In this paper, we present a multipleobjective optimization model for this problem and a two-layer algorithm to solve this model. Experiments on three transportation networks with different network scales are presented to show the excellent performance of the proposed model and algorithm.published_or_final_versio

Enhanced Second-Harmonic Generation in Monolayer MoS2 Driven by a BIC-based Nonlinear Metasurface

Dielectric metasurfaces have opened novel routes for nonlinear optics in recent years. In this work, we integrate a nonlinear metasurface with monolayer molybdenum disulfide (MoS2) to enhance second-harmonic generation (SHG) from atomically thin MoS2. By utilizing bound states in the continuum, we achieve about 600× of SHG enhancement from monolayer MoS2 on a resonant metasurface relative to suspended monolayer MoS2. Moreover, an eigenmode expansion approach is exploited to express second-harmonic power and the corresponding analytical results agree well with the rigorous calculations

All-optical control of topological valley transport in graphene metasurfaces

We demonstrate that the influence of Kerr effect on valley-Hall topological transport in graphene metasurfaces can be used to implement an all-optical switch. In particular, by taking advantage of the large Kerr coefficient of graphene, the index of refraction of a topologically-protected graphene metasurface can be tuned via a pump beam, which results in an optically controllable frequency shift of the photonic bands of the metasurface. This spectral variation can in turn be readily employed to control and switch the propagation of an optical signal in certain waveguide modes of the graphene metasurface. Importantly, our theoretical and computational analysis reveals that the threshold pump power needed to optically switch ON/OFF the signal is strongly dependent on the group velocity of the pump mode, especially when the device is operated in the slow-light regime. This study could open up new routes towards active photonic nanodevices whose underlying functionality stems from their topological characteristics

Evolution of superconductivity in K2-xFe4+ySe5: Spectroscopic studies of X-ray absorption and emission.

This study investigates the evolution of superconductivity in K2-xFe4+ySe5 using temperature-dependent X-ray absorption and resonant inelastic X-ray scattering techniques. Magnetization measurements show that polycrystalline superconducting (SC) K1.9Fe4.2Se5 has a critical temperature (T c) of ∼31 K with a varying superconducting volume fraction, which strongly depends on its synthesis temperature. An increase in Fe-structural/vacancy disorder in SC samples with more Fe atoms occupying vacant 4d sites is found to be closely related to the decrease in the spin magnetic moment of Fe. Moreover, the nearest-neighbor Fe-Se bond length in SC samples exceeds that in the non-SC (NS) sample, K2Fe4Se5, which indicates a weaker hybridization between the Fe 3d and Se 4p states in SC samples. These results clearly demonstrate the correlations among the local electronic and atomic structures and the magnetic properties of K2-xFe4+ySe5 superconductors, providing deeper insight into the electron pairing mechanisms of superconductivity

Minimum thermal conductance in graphene and boron nitride superlattice

The minimum thermal conductance versus supercell size ($d_{s}$) is revealed in graphene and boron nitride superlattice with $d_{s}$ far below the phonon mean free path. The minimum value is reached at a constant ratio of $d_{s}/L\approx 5$, where $L$ is the total length of the superlattice; thus the minimum point of $d_{s}$ depends on $L$. The phenomenon is attributed to the localization property and the number of confined modes in the superlattice. With the increase of $d_{s}$, the localization of the confined mode is enhanced while the number of confined modes decreases, which directly results in the minimum thermal conductance.Comment: accepted by AP